cadmium(Ⅱ)相关论文
Histidine imidazole plays an important role in the synthesize of numerous metalloproteins[1].Therefore,complexes with im......
A 2-fold interpenetrated 3D framework containing semi-rigid bridging ligand:{[Cd2(2-pmip)2(4,4′-bpy)
In the last decade,metal-organic coordination polymers(CPs)with unique architectures and physical properties have afford......
Fluorescence Property Studies of Eight Dinuclear Cadmium(Ⅱ) Complexes Derived from Robson-type Macro
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[Cd(H2O)6]@[Cd6Cl4(nico)12(Hg(Tab)2(μ-Cl))2]a novel heterobimetallic thiolate complex with chlorine-
The design and preparation of heterobimetallic complexes has attracted considerable attention due to their structure......
本研究结合静态实验和X射线吸收精细结构谱学(EXAFS)评估了硫化钼纳米片对重金属Cd(Ⅱ)的吸附行为和微观机制.结果表明:Cd(Ⅱ)在硫......
Syntheses, Crystal Structures and Photoluminescent Properties of Two New 1-D d10 Metal Complexes Bas
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Construction and the Second-order Nonlinear Optics of a New Chiral Coordination Network Based on Two
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利用溴代十六烷基三甲基铵(CTAB)为模板,合成制备了棒状羟基磷灰石颗粒,并以SEM,XRD,IR等手段进行了表征.用制备的羟基磷灰石与自......
Synthesis, Crystal Structure and Fluorescent Property of a New One-dimensional Cadmium(Ⅱ) Coordinati
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Effects of Direction of Bridging of Thiocyanato on the Dimension of Coordination Polymers: Synthesis
Two new cadmium(II)-thiocyanato coordination polymers with 4,4’-dimethyl-2,2’-bipyridine(4,4’-dm-2,2’-bpy) and 4,4’......
Syntheses, Crystal Structures and Characterization of Two Coordination Polymers Based on Mixed Ligan
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目的建立水中痕量镉(Ⅱ)的荧光素-曙红Y能量转移荧光猝灭测定法。方法取0.50ml的水样置于5.0 ml的比色管中,分别加入1×10-4mol/L......
Two Cd(Ⅱ) and Cu(Ⅱ) Complexes Based on 1-Butylbenzimidazole:Crystal Structures and Weak Interactions
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
A New Cadmium(Ⅱ) Coordination Polymer Incorporating a 3D Framework with 1D Channels Bridged by Flexi
The hydrothermal reaction of Cd(OAc)2·2H2O, 4,4'-bpy and cyclohexane-1,2,4,5-tetracarboxylic acid (H4L) yields a three-......
Two mixed-ligand polymeric complexes formulated as {[Zn(pda)(bpy)]·0.5H2O}n (pdathermally synthesized. Single-crystal X......
Synthesis, Characterization and Crystal Structure Determination of a Thiocyanato Bridged One-dimensi
A new one-dimensional polymeric complex [Cd(SCN)2(H2O)]L (L = N,N'-bis(furan-2-ylmethylene)hydrazine) has been synthesiz......
The crystal structure of {[Cd(sulfadiazine)2]n[Cd(sulfadiazine)2·H2O]n} (1) comprises of two different Cd centers in wh......
由水热法得到2个新颖配位聚合物[Cd(2-mba)(bimb)]n(1)和[Pb(2-sb)]n(2)(H2(2-mba)=2-巯基苯甲酸,bimb=4,4-双(1-咪唑基)联苯,sb2-......
A coordination polymer of [Cd{5-(NO2)sal}2(2,2'-bipy)]n (5-(NO2)sal=5-nitrosalicylate, 2,2'-bipy=2,2'-bipyridine) was sy......
将氧化石墨烯(GO)与凹凸棒土(APT)通过插层化学的方法制备了氧化石墨烯/凹凸棒土(GO/APT)复合材料,并研究了其对水中Cd(Ⅱ)的吸附......
由于镉在环境中具有高毒性和生物蓄积性,对人体和环境会产生巨大的危害,因而测定其在环境中的浓度是十分必要的。本研究基于镉(Ⅱ)......
采用天然碳酸盐矿物(方解石、白云石)作为吸附剂,以去除废水中的Cd2+,试验了废水中Cd2+初始浓度、pH值、反应时间、温度及吸附剂粒......
研究了显色剂4－氯－2－磺酸基苯基重氮氨基偶氮苯（CSDAA）的理化性质及其与Cd（Ⅱ）的高灵敏度显色反应。在TritonX-100存在下，于pH10.6的氨水－氯......
用pH－电位滴定法测定了在37℃，μ＝0.1mol/L KNO3,30%二氧六环／水（体积分数）条件下，Cd（IP)(Aa)^+三元配合物的平衡常数lgβ及相对于二元配合......
从不同结构和种类的显色剂及样品的预处理对镉的吸光光度法测定的近年来的进展进行综述(引述文献76篇).......
在阿拉伯树胶存在下的酸性介质中，铋（Ⅲ）、镉（Ⅱ）分别与碘化钾、罗丹明Ｂ形成水溶性的三元离子缔合物，据此提出了测定铋、镉的高灵敏度的分......
The crystal structure of {[Cd(sulfadiazine)2]n[Cd(sulfadiazine)2·H2O]n} (1) comprises of two different Cd centers i......
研究了微乳液介质存在下,在pH=10.8硼砂-NaOH的缓冲溶液中,镉与邻氯苯基荧光酮(o-CPF)显色生成稳定的1:3配合物,在600nm处摩尔吸光......
在0.025mol/L Na_2HPO_4-NaH_2PO_4(pH6.7)介质中,6—巯基嘌呤与镉离子的配合物可在-0.82V(vs SCE)产生灵敏的阴极化波。其二阶导......
本文用pH电位滴定法测定了镉(Ⅰ)-半胱氨酸-组氨酸的各级络合物稳定常数,确定了络合物主要存在形态,通过核磁共振和红外光谱分析了......
